Tem windows


TEMwindows-Silicon_Nitride-Sheet

%PDF-1.5 % 1 0 obj >/OCGs[11 0 R]>>/Pages 3 0 R/Type/Catalog>> endobj 2 0 obj >stream application/pdf

  • TEMwindows-Silicon_Nitride-Sheet
  • 2013-05-01T12:21:04-04:002013-05-01T12:21:04-04:002013-05-01T12:21:04-04:00Adobe Illustrator CS5.1
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    www.temwindows.com

    Silicon TEM windows - EM Resolutions

    Choosing the best Silicon membrane for your application

    The nature of the specimen preparation may determine the choice of membrane. The thermal and chemical stability, surface hydrophobicity, and plasma cleanability differ among the various membranes and should be taken into consideration for each application. The table shows the properties of each membrane type. Click headers in table to view ordering details.

    Amorphous SiliconPorous Nano crystalline SiliconSilicon OxideSilicon Nitride
    Actual thickness (nm)5,9,151520,405,10,20,50
    Image qualityExcellentGoodOKGood
    Plasma cleanableYesYesYesYes
    Elemental analysis BackgroundSi onlySi onlySi, OSi, N
    Thermal stability~600C>1000C>1000C>1000C
    Chemical stabilityAvoid strong basesAvoid strong basesGoodExcellent
    Tolerates High Beam currentsExcellentExcellentOKOK
    Potential contamination sourceNoneNoneNoneNone
    Open Nanoscale poresNoYesNoNo
    BackgroundFeaturelessNano crystallineFeaturelessFeatureless

    /* Here you can add custom CSS for the current table */ /* Lean more about CSS: https://en.wikipedia.org/wiki/Cascading_Style_Sheets */ /* To prevent the use of styles to other tables use "#supsystic-table-2" as a base selector for example: #supsystic-table-2 { ... } #supsystic-table-2 tbody { ... } #supsystic-table-2 tbody tr { ... } */

    Silicon nitride windows can be vigorously plasma cleaned to remove organic contamination. They give reduced field-to-field variability with less than 0.5nm variation in thickness across an entire production batch, not just a single window. Incorporates LPCVD, low-stress (~250MPa), non-stoichiometric silicon nitride: providing flat, insulating and hydrophobic surfaces. Download handling instructions here
    Slots or squares?

    TEM windows are available in an assortment of geometries including standard two slot or nine square formations. Due to the geometry, the squares will be slightly more robust and more likely to survive rigorous sample preparation. The slots allow larger uninterrupted viewing windows.

    /* Here you can add custom CSS for the current table */ /* Lean more about CSS: https://en.wikipedia.org/wiki/Cascading_Style_Sheets */ /* To prevent the use of styles to other tables use "#supsystic-table-1" as a base selector for example: #supsystic-table-1 { ... } #supsystic-table-1 tbody { ... } #supsystic-table-1 tbody tr { ... } */

    Choice of membrane thickness

    The choice of membrane thickness and type is dependent on many variables. Thinner membranes (5-10 nm) are more suitable for higher resolution imaging, while thicker membranes (15-50 nm) are better for demanding sample preparation procedures. You should consider using a thicker membrane for method development and moving to thinner membranes for final imaging.

    • 5nm for the highest resolution imaging
    • 10nm for high resolution with increased robustness
    • 20nm for everyday imaging
    • 50nm for the most demanding conditions
    • Microporous for suspension of materials and Cryo-TEM

     

    Silicon Nitride membranes (TEM windows) have the advantage of being chemically inert and mechanically robust, being able to withstand temperatures >1000°C. They are particularly suitable for conducting nanotechnology experiments directly on their surface over a wide temperature range.

    Microporous windows have 2 micron pores that are patterned in 50 nm silicon nitride in a gridded pattern within a single 500 x 500 micron window. These microporous windows can be used for suspending a variety of thin films such as graphene as demonstrated in the Nature paper cited below. These films are also used for Cryo EM as well as high-tilt tomography. At 70 degree angles, the thin and bevelled 100 micron silicon frame allows you to use a ~50×50 micron region within the centre of the window from any rotational orientation.

    Grains and grain boundaries in single-layer graphene atomic patchwork quilts Pinshane Y. Huang,, Carlos S. Ruiz-Vargas,, Arend M. van der Zande,,William S. Whitney,, Mark P. Levendorf,, Joshua W. Kevek,, Shivank Garg, Jonathan S. Alden,, Caleb J. Hustedt,, Ye Zhu,, Jiwoong Park,, Paul L. McEuen, & David A. Muller    Nature:469, :389–392 (20 January 2011)

     

    Substrates for High-Resolution Imaging

    The following TEM Window grids are recommended for high-resolution imaging of nanoparticles or nanotubes:

    5 nm Pure Silicon TEM Windows 

    Electron Tomography at 2.4A Resolution

    Scott et al. (2012) Nature. 483: 444-447

    Direct imaging and chemical analysis of unsustained DNA origami performed with a Transmission Electron Microscope

    Alloyeau et al. (2011) Chemical Communications. 47: 9375-9377

    Revealing Correlation of Valence State with Nanoporous Structure in Cobalt Catalyst Nanoparticles by In Situ Environmental TEM

    Xin et al. (2012) ACS Nano. 6: 4241-4247

     

    5 or 10 nm Silicon Nitride TEM windows 

    Twinning and Twisting of Tri- and Bilayer Graphene

    Brown et al. (2012) Nano Letters. 12(3):1609-1615

    Three-dimensional Imaging of Dislocations in a Nanoparticle at atomic Resolution

    Chen et al. (2013) Nature. 496(7443): 74-77

    Grains and Grain Boundaries in Highly Crystalline Monolayer Molybdenum Disulphide

    Van der Zande et al. (2013) Nature Materials. 12: 554-561

    Tailoring Electrical Transport across Grain Boundaries in Polycrystalline Graphene

    Tsen et al. (2012) Science.  336: 1143-1146

    emresolutions.com

    TEMwindows-Handling

    %PDF-1.5 % 1 0 obj >/OCGs[10 0 R 56 0 R 102 0 R]>>/Pages 3 0 R/Type/Catalog>> endobj 2 0 obj >stream application/pdf

  • TEMwindows-Handling
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